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Volume 6
Issue 1
Online publication date 2012-03-20
Title Phosphorus-contained polycondensation type ion-exchange resins
Author Tulkun Tursunov
Abstract
This work describes synthesis and research of new polycondensation type phosphorus-contained ion-exchange polymers by phosphorylation of polymers received through the interaction of furfural (accessible and cheap product of hydrolytic and cotton scraping industry of Uzbekistan) with benzyl bromide (chloride). Furfural and its derivatives possess high reactionary ability thanks to presence of carbonyl groups, and presence of a heterocyclic cycle gives to the received polymers high thermal and chemical stability. Polycondensation reaction kinetics of furfural and benzyl bromide, and phosphorylation reaction of the received benzyl bromide-furfural polymer were studied. Sorption, kinetic and thermo-chemical properties of received ion-exchange resins were studied using physico-chemical and chemical analyses to find out specific objects of practical application. Particularly, sorption and selective properties of received ion-exchange resins to ions of such metals as copper, nickel, calcium, magnesium, and uranyl ion were studied. Received results support the application of the investigated ion-exchange resins in processes of clearing of industrial and waste waters of hydrometallurgical manufactures.
Citation
References
Pulatov, H., Tursunov, T., Nazirova, R., 2006. “Research new monofunctional sulfonic acid cation-exchange resins and their use in processes of softening waters,” Chemistry and Chemical Technology [Khimiya i Khimicheskaya Tekhnologiya], in Russian, pp.65-67

Sherbakov, A., 1962. Furfural [Furfurol], in Russian, Kiev
Tursunov, T., Nazirova, R., 1985a. “Thermal stability of ion-exchange resin on a basis of furfural,” Uzbek Chemical Journal [Uzbekskiy Khimicheskiy Jurnal], in Russian, No.4, pp.71-72

Tursunov, T., Nazirova, R., 1985b. “Synthesis of ion-exchange resin by chemical transformation of products of polycondensation of furfural and halogen benzenes,” Uzbek Chemical Journal [Uzbekskiy Khimicheskiy Jurnal], in Russian, No.3, pp.48-50

Tursunov, T., Nazirova, R., 1985c. “Synthesis nitrogen-fosforus-contained ion-exchange resins,” Uzbek Chemical Journal [Uzbekskiy Khimicheskiy Jurnal], in Russian, No.5, pp.65-66

Tursunov, T., Nazirova, R., 1978. A way of reception of amphoteric resin [Sposob poluchyeniya amfotyernogo ionita], Certificate of authorship, No.512215, Uzbekistan

Tursunov, T., 2009. “Phosphorylation of polymer on a basis of furfural and bromous benzyl,” Chemistry and Chemical Technology [Kimyo va kimyo texnologiyasi], in Uzbek, No.4, pp.54-56

Tursunov, T., Zajnutdinova, B., Nazirova, R., 1999. “Synthesis of polycondensation anion-exchange resins containing high-base groups,” Bulletin of TSTU [Vestnik TashGTU], in Russian, No.3,  pp.135-40

Turobjonov, S., Pulatov, H., Tursunov, T., Nazirova, R., Mutalov, Sh., 2005. Method of reception of cation-exchange resins [Sposob poluchyeniya kationitov], in Russian, Patent, Republic of Uzbekistan, RUz IAP 03458

Tursunov, T., Mirkamilov, T., Nazirova, R., 1995. “Research in the field of reception and application of ion-exchange polymers on a basis furan compounds,” Materials of conference “Topical problems of polymer science” [Polimyerlar faniningu zamonaviy muommolari], in Uzbek, Tashkent, pp.28-30

Tursunov, T., Gabrielyan, N., Suhinina, L., 1974.  “Potentiometrical researches of sorption abilities of furan anion-exchange resins,” Collection “Research of properties and application of polymeric materials” [Isslyedovaniye svoystv i primenyeniye polimernikh materialov], in Russian, Moscow
Keywords Furfural, benzyl bromide, ion-exchange resin, cation-exchange resin, polycondensation, sorption, phosphorylation, copper, nickel, calcium, magnesium, uranil ion, benzyl bromide-furfural polymer, bromomethyl group, polyethylene polyamine, potentiometric titration, thermal stability, chemical stability
DOI http://dx.doi.org/10.15208/ati.2012.2
Pages 10-21
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